JAJ
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Back in the 1980's I was chief engineer of a company that made some pretty sophisticated electronic equipment that was big, heavy and produced a lot of heat when it was in operation. We used a lot of different plastics in the manufacturing, so I'm pretty familiar with resins and how they work. Part of my job was to figure out which ones to use and how to use them - reinforce them, leave them alone, hot or cold cure, all that stuff. To get regulatory approval we had to test some items to destruction, in the sense that we had to prove it wouldn't burn under the most extreme conditions it could encounter. Resins and reinforced plastics are not a mystery.Resins are what hold all carbon composites together and are a key component to the strength and stiffness of composites. That's why when a carbon fiber race car burns down, all that's left is the carbon fibers themselves that is as flimsy as it was before the resins were added at the beginning of manufacturing. There's a big difference from saying the "Carbon" is what burns off vs the "Resin". That's a fundamental understanding of composites. You also need to acknowledge the resin and loss of mass from the center of the rotor due to heat. It's not just the surface.
The thing with carbon ceramic brake rotors is that, according to Brembo SGL and Surface Transforms, the manufacturing process turns "the resin" into pure carbon. If you dig around the internet a bit, you'll find an industrial process called "Polymer-to-Carbon Conversion" which converts a polymer resin into a form of carbon called "glassy carbon" with characteristics similar to the carbon crystals described below in the Surface Transforms quote.
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213281/
The Brembo SGL website describes their manufacturing process as "The production process of the ceramic brake body requires a preform pressed with binding resin to a so called green body which will be converted in the ceramic component by first carbonizing at 900 °C and second by liquid silicon infiltration (siliconization) at 1700 °C in vacuum atmosphere."
The Surface Transforms website describes carbonizing as "...the pre-forms are heated, they begin to lose their non-carbon atoms, plus a few carbon atoms, in the form of various gases including water vapor, ammonia, carbon monoxide, carbon dioxide, hydrogen, nitrogen, and others. As the non-carbon atoms are expelled, the remaining carbon atoms form tightly bonded carbon crystals"
Because carbonizing drives off a lot of the original chemicals that made up the resin, it leaves the ceramic body porous, like a really hard sponge, with microscopic spaces throughout the material. ST fills these spaces with silicon carbide while SGL uses liquid silicon (not silicone, the plastic, but elemental silicon, the stuff that computer chips and glass are made from).
That's why carbon ceramic rotors are hard to make, but it's also why they perform the way they do. By the end of the manufacturing cycle, they're made of carbon fiber, carbon crystals, silicon and silicon carbide. There are three different forms of carbon in the product. From the standpoint of weight loss from high temperature use, the silicon carbide and silicon are immune - they don't break down or vaporize until they're in the thousands of degrees.
That leaves the carbon fiber and the carbon crystals as candidates to explain why rotors get lighter as they get used up. SGL says "we use carbon fibers which are given a special protective coating", so for a Brembo SGL rotor, the only things left that can oxidize are the carbon crystals that are spread throughout the ceramic structure. If you get the rotor hot enough, the carbon oxidizes and departs in the form of carbon dioxide, leaving voids in the structure (it becomes a sponge again) making the rotor lighter. "Hot enough" seems to be around 700 to 900 degrees C, depending who made the rotor.
And of course, if the rotor gets hot enough all the way through, it will lose mass all the way through, not just on the surface.
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